Home Research Catalysis Bio-inspired Catalysis with Soluble Polymer Nanoreactors
Bio-inspired Catalysis with Soluble Polymer Nanoreactors PDF Print E-mail
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Friday, 14 March 2008 11:45

Robin Chi, Steve Scroggins, Emine Boz

 

Program Overview: Towards mimicking nature's ability in one-pot catalytic synthesis of complex molecules from simple substrates, in an efficient, clean, and sustainable manner

Nanoreactor Scheme


A model system: Enzyme-like one-pot asymmetric catalysis
with non-interpenetrating soluble polymer nanoreactor

Nanoreactor Catalysis Reaction Scheme

How does it work: designed star polymer catalysts allow one-pot combination of normally incompatible catalysts

Full Reaction Scheme

Control experiments replacing star polymer catalysts with the corresponding small molecule or linear polymer analogs lead to little or no cascade reaction
Last Updated on Wednesday, 03 September 2008 13:02
 
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